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The valence orbitals of an atom surrounded by a tetrahedral arrangement of bonding pairs and lone pairs consist of a set of four sp 3 hybrid orbitals . The hybrids result from the mixing of one s orbital and all three p orbitals that produces four identical sp 3 hybrid orbitals ( [link] ). Each of these hybrid orbitals points toward a different corner of a tetrahedron.
A molecule of methane, CH 4 , consists of a carbon atom surrounded by four hydrogen atoms at the corners of a tetrahedron. The carbon atom in methane exhibits sp 3 hybridization. We illustrate the orbitals and electron distribution in an isolated carbon atom and in the bonded atom in CH 4 in [link] . The four valence electrons of the carbon atom are distributed equally in the hybrid orbitals, and each carbon electron pairs with a hydrogen electron when the C–H bonds form.
In a methane molecule, the 1 s orbital of each of the four hydrogen atoms overlaps with one of the four sp 3 orbitals of the carbon atom to form a sigma (σ) bond. This results in the formation of four strong, equivalent covalent bonds between the carbon atom and each of the hydrogen atoms to produce the methane molecule, CH 4 .
The structure of ethane, C 2 H 6, is similar to that of methane in that each carbon in ethane has four neighboring atoms arranged at the corners of a tetrahedron—three hydrogen atoms and one carbon atom ( [link] ). However, in ethane an sp 3 orbital of one carbon atom overlaps end to end with an sp 3 orbital of a second carbon atom to form a σ bond between the two carbon atoms. Each of the remaining sp 3 hybrid orbitals overlaps with an s orbital of a hydrogen atom to form carbon–hydrogen σ bonds. The structure and overall outline of the bonding orbitals of ethane are shown in [link] . The orientation of the two CH 3 groups is not fixed relative to each other. Experimental evidence shows that rotation around σ bonds occurs easily.
An sp 3 hybrid orbital can also hold a lone pair of electrons. For example, the nitrogen atom in ammonia is surrounded by three bonding pairs and a lone pair of electrons directed to the four corners of a tetrahedron. The nitrogen atom is sp 3 hybridized with one hybrid orbital occupied by the lone pair.
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