<< Chapter < Page Chapter >> Page >

Nitrates , salts of nitric acid, form when metals, oxides, hydroxides, or carbonates react with nitric acid. Most nitrates are soluble in water; indeed, one of the significant uses of nitric acid is to prepare soluble metal nitrates.

Nitric acid finds extensive use in the laboratory and in chemical industries as a strong acid and strong oxidizing agent. It is important in the manufacture of explosives, dyes, plastics, and drugs. Salts of nitric acid (nitrates) are valuable as fertilizers. Gunpowder is a mixture of potassium nitrate, sulfur, and charcoal.

The reaction of N 2 O 3 with water gives a pale blue solution of nitrous acid, HNO 2 . However, HNO 2 (shown in [link] ) is easier to prepare by the addition of an acid to a solution of nitrite; nitrous acid is a weak acid, so the nitrite ion is basic in aqueous solution:

NO 2 ( a q ) + H 3 O + ( a q ) HNO 2 ( a q ) + H 2 O ( l )

Nitrous acid is very unstable and exists only in solution. It disproportionates slowly at room temperature (rapidly when heated) into nitric acid and nitric oxide. Nitrous acid is an active oxidizing agent with strong reducing agents, and strong oxidizing agents oxidize it to nitric acid.

A space filling model shows a blue atom labeled, “N,” bonded on two sides to red atoms labeled, “O.” One of the red atoms is bonded to a white atom labeled, “H.”
This image shows the molecular structure of a molecule of nitrous acid, HNO 2 .

Sodium nitrite, NaNO 2 , is an additive to meats such as hot dogs and cold cuts. The nitrite ion has two functions. It limits the growth of bacteria that can cause food poisoning, and it prolongs the meat’s retention of its red color. The addition of sodium nitrite to meat products is controversial because nitrous acid reacts with certain organic compounds to form a class of compounds known as nitrosamines. Nitrosamines produce cancer in laboratory animals. This has prompted the FDA to limit the amount of NaNO 2 in foods.

The nitrites are much more stable than the acid, but nitrites, like nitrates, can explode. Nitrites, like nitrates, are also soluble in water (AgNO 2 is only slightly soluble).

Phosphorus oxyacids and salts

Pure orthophosphoric acid, H 3 PO 4 (shown in [link] ), forms colorless, deliquescent crystals that melt at 42 °C. The common name of this compound is phosphoric acid, and is commercially available as a viscous 82% solution known as syrupy phosphoric acid. One use of phosphoric acid is as an additive to many soft drinks.

One commercial method of preparing orthophosphoric acid is to treat calcium phosphate rock with concentrated sulfuric acid:

Ca 3 ( PO 4 ) 2 ( s ) + 3 H 2 SO 4 ( a q ) 2 H 3 PO 4 ( a q ) + 3 CaSO 4 ( s )
A space filling model shows an orange atom labeled, “P,” bonded on four sides to red atoms labeled, “O.” Three of the red atoms are bonded to white atoms labeled, “H.” A Lewis structure is also shown in which a phosphorus atom is single bonded to four oxygen atoms, three of which have two lone pairs of electrons, and one of which has three lone pairs of electrons. The oxygen atoms with two lone pairs of electrons are single bonded to hydrogen atoms.
Orthophosphoric acid, H 3 PO 4 , is colorless when pure and has this molecular (left) and Lewis structure (right).

Dilution of the products with water, followed by filtration to remove calcium sulfate, gives a dilute acid solution contaminated with calcium dihydrogen phosphate, Ca(H 2 PO 4 ) 2 , and other compounds associated with calcium phosphate rock. It is possible to prepare pure orthophosphoric acid by dissolving P 4 O 10 in water.

Questions & Answers

Discuss the differences between taste and flavor, including how other sensory inputs contribute to our  perception of flavor.
John Reply
taste refers to your understanding of the flavor . while flavor one The other hand is refers to sort of just a blend things.
Faith
While taste primarily relies on our taste buds, flavor involves a complex interplay between taste and aroma
Kamara
which drugs can we use for ulcers
Ummi Reply
omeprazole
Kamara
what
Renee
what is this
Renee
is a drug
Kamara
of anti-ulcer
Kamara
Omeprazole Cimetidine / Tagament For the complicated once ulcer - kit
Patrick
what is the function of lymphatic system
Nency Reply
Not really sure
Eli
to drain extracellular fluid all over the body.
asegid
The lymphatic system plays several crucial roles in the human body, functioning as a key component of the immune system and contributing to the maintenance of fluid balance. Its main functions include: 1. Immune Response: The lymphatic system produces and transports lymphocytes, which are a type of
asegid
to transport fluids fats proteins and lymphocytes to the blood stream as lymph
Adama
what is anatomy
Oyindarmola Reply
Anatomy is the identification and description of the structures of living things
Kamara
what's the difference between anatomy and physiology
Oyerinde Reply
Anatomy is the study of the structure of the body, while physiology is the study of the function of the body. Anatomy looks at the body's organs and systems, while physiology looks at how those organs and systems work together to keep the body functioning.
AI-Robot
what is enzymes all about?
Mohammed Reply
Enzymes are proteins that help speed up chemical reactions in our bodies. Enzymes are essential for digestion, liver function and much more. Too much or too little of a certain enzyme can cause health problems
Kamara
yes
Prince
how does the stomach protect itself from the damaging effects of HCl
Wulku Reply
little girl okay how does the stomach protect itself from the damaging effect of HCL
Wulku
it is because of the enzyme that the stomach produce that help the stomach from the damaging effect of HCL
Kamara
function of digestive system
Ali Reply
function of digestive
Ali
the diagram of the lungs
Adaeze Reply
what is the normal body temperature
Diya Reply
37 degrees selcius
Xolo
37°c
Stephanie
please why 37 degree selcius normal temperature
Mark
36.5
Simon
37°c
Iyogho
the normal temperature is 37°c or 98.6 °Fahrenheit is important for maintaining the homeostasis in the body the body regular this temperature through the process called thermoregulation which involves brain skin muscle and other organ working together to maintain stable internal temperature
Stephanie
37A c
Wulku
what is anaemia
Diya Reply
anaemia is the decrease in RBC count hemoglobin count and PVC count
Eniola
what is the pH of the vagina
Diya Reply
how does Lysin attack pathogens
Diya
acid
Mary
I information on anatomy position and digestive system and there enzyme
Elisha Reply
anatomy of the female external genitalia
Muhammad Reply
Organ Systems Of The Human Body (Continued) Organ Systems Of The Human Body (Continued)
Theophilus Reply
what's lochia albra
Kizito
Got questions? Join the online conversation and get instant answers!
Jobilize.com Reply

Get Jobilize Job Search Mobile App in your pocket Now!

Get it on Google Play Download on the App Store Now




Source:  OpenStax, Chemistry. OpenStax CNX. May 20, 2015 Download for free at http://legacy.cnx.org/content/col11760/1.9
Google Play and the Google Play logo are trademarks of Google Inc.

Notification Switch

Would you like to follow the 'Chemistry' conversation and receive update notifications?

Ask