<< Chapter < Page Chapter >> Page >
introduction to semiconductors, mainly looking at the behavior of electrons in a solid from a quantum mechanical point of view.

If we only had to worry about simple conductors, life would not be very complicated, but on the other hand we wouldn't be ableto make computers, CD players, cell phones, i-Pods and a lot of other things which we have found to be useful. We will now move on,and talk about another class of conductors called semiconductors.

In order to understand semiconductors and in fact to get a more accurate picture of how metals, or normal conductors actuallywork, we really have to resort to quantum mechanics. Electrons in a solid are very tiny objects, and it turns out that whenthings get small enough, they no longer exactly following the classical "Newtonian" laws of physics that we are all familiarwith from everyday experience. It is not the purpose of this course to teach you quantum mechanics, so what we are going todo instead is describe the results which come from looking at the behavior of electrons in a solid from a quantum mechanicalpoint of view.

Solids (at least the ones we will be talking about, and especially semiconductors) are crystalline materials, whichmeans that they have their atoms arranged in a ordered fashion. We can take silicon (the most important semiconductor)as an example. Silicon is a group IV element, which means it has four electrons in its outer or valence shell. Siliconcrystallizes in a structure called the diamond crystal lattice. This is shown in . Each silicon atom has four covalent bonds, arranged in atetrahedral formation about the atom center.

Crystal structure of silicon
In two dimensions, we can schematically represent a piece of single-crystal silicon as shown in . Each silicon atom shares its four valence electrons with valenceelectrons from four nearest neighbors, filling the shell to 8 electrons, and forming a stable, periodic structure. Once theatoms have been arranged like this, the outer valence electrons are no longer strongly bound to the host atom. The outer shellsof all of the atoms blend together and form what is called a band . The electrons are now free to move about within this band, and this can lead to electrical conductivityas we discussed earlier.
A 2-D representation of a silicon crystal
This is not the complete story however, for it turns out that due to quantum mechanical effects, there is not just one bandwhich holds electrons, but several of them. What will follow is a very qualitative picture of how the electrons are distributedwhen they are in a periodic solid, and there are necessarily some details which we will be forced to gloss over. On theother hand this will give you a pretty good picture of what is going on, and may enable you to have some understanding of how asemiconductor really works. Electrons are not only distributed throughout the solid crystal spatially, but they also have a distribution in energyas well. The potential energy function within the solid is periodic in nature. This potential function comes from thepositively charged atomic nuclei which are arranged in the crystal in a regular array. A detailed analysisof how electron wave functions , the mathematical abstraction which one must use to describe how small quantummechanical objects behave when they are in a periodic potential, gives rise to an energy distribution somewhat like that shown in .
Schematic of the first two bands in a periodic solid showing energy levels and bands
Firstly, unlike the case for free electrons, in a periodic solid, electrons are not free to take on any energy value they wish.They are forced into specific energy levels called allowed states which are represented by the cups in the figure. The allowed states are not distributed uniformly in energy either. They are grouped into specific configurationscalled energy bands . There are no allowed levels at zero energy and for some distance above that. Moving up fromzero energy, we then encounter the first energy band. At the bottom of the band there are very few allowed states, but as wemove up in energy, the number of allowed states first increases, and then falls off again. We then come to a region with noallowed states, called an energy band gap . Above the band gap, another band of allowed states exists. This goes on and on,with any given material having many such bands and band gaps. This situation is shown schematically in , where the small cups represent allowed energy levels, and the vertical axis represents electron energy.

Questions & Answers

how to create a software using Android phone
Wiseman Reply
how
basra
what is the difference between C and C++.
Yan Reply
what is software
Sami Reply
software is a instructions like programs
Shambhu
what is the difference between C and C++.
Yan
yes, how?
Hayder
what is software engineering
Ahmad
software engineering is a the branch of computer science deals with the design,development, testing and maintenance of software applications.
Hayder
who is best bw software engineering and cyber security
Ahmad
Both software engineering and cybersecurity offer exciting career prospects, but your choice ultimately depends on your interests and skills. If you enjoy problem-solving, programming, and designing software syste
Hayder
what's software processes
Ntege Reply
I haven't started reading yet. by device (hardware) or for improving design Lol? Here. Requirement, Design, Implementation, Verification, Maintenance.
Vernon
I can give you a more valid answer by 5:00 By the way gm.
Vernon
it is all about designing,developing, testing, implementing and maintaining of software systems.
Ehenew
hello assalamualaikum
Sami
My name M Sami I m 2nd year student
Sami
what is the specific IDE for flutter programs?
Mwami Reply
jegudgdtgd my Name my Name is M and I have been talking about iey my papa john's university of washington post I tagged I will be in
Mwaqas Reply
yes
usman
how disign photo
atul Reply
hlo
Navya
hi
Michael
yes
Subhan
Show the necessary steps with description in resource monitoring process (CPU,memory,disk and network)
samuel Reply
What is software engineering
Tafadzwa Reply
Software engineering is a branch of computer science directed to writing programs to develop Softwares that can drive or enable the functionality of some hardwares like phone , automobile and others
kelvin
if any requirement engineer is gathering requirements from client and after getting he/she Analyze them this process is called
Alqa Reply
The following text is encoded in base 64. Ik5ldmVyIHRydXN0IGEgY29tcHV0ZXIgeW91IGNhbid0IHRocm93IG91dCBhIHdpbmRvdyIgLSBTdGV2ZSBXb3puaWFr Decode it, and paste the decoded text here
Julian Reply
what to do you mean
Vincent
hello
ALI
how are you ?
ALI
What is the command to list the contents of a directory in Unix and Unix-like operating systems
George Reply
how can i make my own software free of cost
Faizan Reply
like how
usman
hi
Hayder
The name of the author of our software engineering book is Ian Sommerville.
Doha Reply
what is software
Sampson Reply
the set of intruction given to the computer to perform a task
Noor
Got questions? Join the online conversation and get instant answers!
Jobilize.com Reply

Get Jobilize Job Search Mobile App in your pocket Now!

Get it on Google Play Download on the App Store Now




Source:  OpenStax, Introduction to physical electronics. OpenStax CNX. Sep 17, 2007 Download for free at http://cnx.org/content/col10114/1.4
Google Play and the Google Play logo are trademarks of Google Inc.

Notification Switch

Would you like to follow the 'Introduction to physical electronics' conversation and receive update notifications?

Ask