-
Home
- Chemistry
- Liquids and solids
- Lattice structures in crystalline
Key concepts and summary
The structures of crystalline metals and simple ionic compounds can be described in terms of packing of spheres. Metal atoms can pack in hexagonal closest-packed structures, cubic closest-packed structures, body-centered structures, and simple cubic structures. The anions in simple ionic structures commonly adopt one of these structures, and the cations occupy the spaces remaining between the anions. Small cations usually occupy tetrahedral holes in a closest-packed array of anions. Larger cations usually occupy octahedral holes. Still larger cations can occupy cubic holes in a simple cubic array of anions. The structure of a solid can be described by indicating the size and shape of a unit cell and the contents of the cell. The type of structure and dimensions of the unit cell can be determined by X-ray diffraction measurements.
Key equations
Chemistry end of chapter exercises
Describe the crystal structure of iron, which crystallizes with two equivalent metal atoms in a cubic unit cell.
The structure of this low-temperature form of iron (below 910 °C) is body-centered cubic. There is one-eighth atom at each of the eight corners of the cube and one atom in the center of the cube.
Got questions? Get instant answers now!
Tungsten crystallizes in a body-centered cubic unit cell with an edge length of 3.165 Å.
(a) What is the atomic radius of tungsten in this structure?
(b) Calculate the density of tungsten.
(a) 1.370 Å; (b) 19.26 g/cm
Got questions? Get instant answers now!
Platinum (atomic radius = 1.38 Å) crystallizes in a cubic closely packed structure. Calculate the edge length of the face-centered cubic unit cell and the density of platinum.
Got questions? Get instant answers now!
Barium crystallizes in a body-centered cubic unit cell with an edge length of 5.025 Å
(a) What is the atomic radius of barium in this structure?
(b) Calculate the density of barium.
(a) 2.176 Å; (b) 3.595 g/cm
3
Got questions? Get instant answers now!
Aluminum (atomic radius = 1.43 Å) crystallizes in a cubic closely packed structure. Calculate the edge length of the face-centered cubic unit cell and the density of aluminum.
Got questions? Get instant answers now!
The density of aluminum is 2.7 g/cm
3 ; that of silicon is 2.3 g/cm
3 . Explain why Si has the lower density even though it has heavier atoms.
The crystal structure of Si shows that it is less tightly packed (coordination number 4) in the solid than Al (coordination number 12).
Got questions? Get instant answers now!
The free space in a metal may be found by subtracting the volume of the atoms in a unit cell from the volume of the cell. Calculate the percentage of free space in each of the three cubic lattices if all atoms in each are of equal size and touch their nearest neighbors. Which of these structures represents the most efficient packing? That is, which packs with the least amount of unused space?
Got questions? Get instant answers now!
Questions & Answers
what does preconceived mean
How can I develope my cognitive domain
why is communication effective
Communication is effective because it allows individuals to share ideas, thoughts, and information with others.
effective communication can lead to improved outcomes in various settings, including personal relationships, business environments, and educational settings. By communicating effectively, individuals can negotiate effectively, solve problems collaboratively, and work towards common goals.
it starts up serve and return practice/assessments.it helps find voice talking therapy also assessments through relaxed conversation.
miss
Every time someone flushes a toilet in the apartment building, the person begins to jumb back automatically after hearing the flush, before the water temperature changes. Identify the types of learning, if it is classical conditioning identify the NS, UCS, CS and CR. If it is operant conditioning, identify the type of consequence positive reinforcement, negative reinforcement or punishment
please i need answer
Wekolamo
because it helps many people around the world to understand how to interact with other people and understand them well, for example at work (job).
Agreed 👍 There are many parts of our brains and behaviors, we really need to get to know. Blessings for everyone and happy Sunday!
ARC
A child is a member of community not society elucidate ?
Isn't practices worldwide, be it psychology, be it science. isn't much just a false belief of control over something the mind cannot truly comprehend?
compare and contrast skinner's perspective on personality development on freud
Skinner skipped the whole unconscious phenomenon and rather emphasized on classical conditioning
war
explain how nature and nurture affect the development and later the productivity of an individual.
nature is an hereditary factor while nurture is an environmental factor which constitute an individual personality. so if an individual's parent has a deviant behavior and was also brought up in an deviant environment, observation of the behavior and the inborn trait we make the individual deviant.
Samuel
I am taking this course because I am hoping that I could somehow learn more about my chosen field of interest and due to the fact that being a PsyD really ignites my passion as an individual the more I hope to learn about developing and literally explore the complexity of my critical thinking skills
and having a good philosophy of the world is like a sandwich and a peanut butter 👍
Jonathan
generally amnesi how long yrs memory loss
interpersonal relationships
What would be the best educational aid(s) for gifted kids/savants?
treat them normal, if they want help then give them.
that will make everyone happy
Saurabh
What are the treatment for autism?
hello. autism is a umbrella term. autistic kids have different disorder overlapping. for example. a kid may show symptoms of ADHD and also learning disabilities.
before treatment please make sure the kid doesn't have physical disabilities like hearing..vision..speech problem. sometimes these
Jharna
continue..
sometimes due to these physical problems..the diagnosis may be misdiagnosed.
treatment for autism.
well it depends on the severity.
since autistic kids have problems in communicating and adopting to the environment.. it's best to expose the child in situations where the child
Jharna
child interact with other kids under doc supervision.
play therapy.
speech therapy.
Engaging in different activities that activate most parts of the brain.. like drawing..painting. matching color board game.
string and beads game.
the more you interact with the child the more effective
Jharna
results you'll get..
please consult a therapist to know what suits best on your child.
and last as a parent. I know sometimes it's overwhelming to guide a special kid.
but trust the process and be strong and patient as a parent.
Jharna
Got questions? Join the online conversation and get instant answers!
Source:
OpenStax, Chemistry. OpenStax CNX. May 20, 2015 Download for free at http://legacy.cnx.org/content/col11760/1.9
Google Play and the Google Play logo are trademarks of Google Inc.
