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Standard Electrode (Half-Cell) Potentials
Half-Reaction E ° (V)
Ag + + e Ag +0.7996
AgCl + e Ag + Cl +0.22233
[ Ag ( CN ) 2 ] + e Ag + 2 CN −0.31
Ag 2 CrO 4 + 2 e 2 Ag + CrO 4 2− +0.45
[ Ag ( NH 3 ) 2 ] + + e Ag + 2 NH 3 +0.373
[ Ag ( S 2 O 3 ) 2 ] 3+ + e Ag + 2S 2 O 3 2− +0.017
[ AlF 6 ] 3− + 3 e Al + 6 F −2.07
Al 3+ + 3 e Al −1.662
Am 3+ + 3 e Am −2.048
Au 3+ + 3 e Au +1.498
Au + + e Au +1.692
Ba 2+ + 2 e Ba −2.912
Be 2+ + 2 e Be −1.847
Br 2 ( a q ) + 2 e 2 Br +1.0873
Ca 2+ + 2 e Ca −2.868
Ce 3 + 3 e Ce −2.483
Ce 4+ + e Ce 3+ +1.61
Cd 2+ + 2 e Cd −0.4030
[ Cd ( CN ) 4 ] 2− + 2 e Cd + 4 CN −1.09
[ Cd ( NH 3 ) 4 ] 2+ + 2 e Cd + 4 NH 3 −0.61
CdS + 2 e Cd + S 2− −1.17
Cl 2 + 2 e 2 Cl +1.35827
ClO 4 + H 2 O + 2 e ClO 3 + 2 OH +0.36
ClO 3 + H 2 O + 2 e ClO 2 + 2 OH +0.33
ClO 2 + H 2 O + 2 e ClO + 2 OH +0.66
ClO + H 2 O + 2 e Cl + 2 OH +0.89
ClO 4 + 2 H 3 O + + 2 e ClO 3 + 3 H 2 O +1.189
ClO 3 + 3 H 3 O + + 2 e HClO 2 + 4 H 2 O +1.21
HClO + H 3 O + + 2 e Cl + 2 H 2 O +1.482
HClO + H 3 O + + e 1 2 Cl 2 + 2 H 2 O +1.611
HClO 2 + 2 H 3 O + + 2 e HClO + 3 H 2 O +1.628
Co 3+ + e Co 2+ ( 2 mol // H 2 SO 4 ) +1.83
Co 2+ + 2 e Co −0.28
[ Co ( NH 3 ) 6 ] 3+ + e [ Co ( NH 3 ) 6 ] 2+ +0.1
Co ( OH ) 3 + e Co ( OH ) 2 + OH +0.17
Cr 3 + 3 e Cr −0.744
Cr 3+ + e Cr 2+ −0.407
Cr 2+ + 2 e Cr −0.913
[ Cu ( CN ) 2 ] + e Cu + 2 CN −0.43
CrO 4 2− + 4 H 2 O + 3 e Cr ( OH ) 3 + 5 OH −0.13
Cr 2 O 7 2− + 14 H 3 O + + 6 e 2 Cr 3+ + 21 H 2 O +1.232
[ Cr ( OH ) 4 ] + 3 e Cr + 4 OH −1.2
Cr ( OH ) 3 + 3 e Cr + 3 OH −1.48
Cu 2+ + e Cu + +0.153
Cu 2+ + 2 e Cu +0.34
Cu + + e Cu +0.521
F 2 + 2 e 2 F +2.866
Fe 2+ + 2 e Fe −0.447
Fe 3+ + e Fe 2+ +0.771
[ Fe ( CN ) 6 ] 3− + e [ Fe ( CN ) 6 ] 4− +0.36
Fe ( OH ) 2 + 2 e Fe + 2 OH −0.88
FeS + 2 e Fe + S 2− −1.01
Ga 3+ + 3 e Ga −0.549
Gd 3+ + 3 e Gd −2.279
1 2 H 2 + e H −2.23
2 H 2 O + 2 e H 2 + 2 OH −0.8277
H 2 O 2 + 2 H 3 O + + 2 e 4 H 2 O +1.776
2 H 3 O + + 2 e H 2 + 2 H 2 O 0.00
HO 2 + H 2 O + 2 e 3 OH +0.878
Hf 4+ + 4 e Hf −1.55
Hg 2+ + 2 e Hg +0.851
2 Hg 2+ + 2 e Hg 2 2+ +0.92
Hg 2 2+ + 2 e 2 Hg +0.7973
[ HgBr 4 ] 2− + 2 e Hg + 4 Br +0.21
Hg 2 Cl 2 + 2 e 2 Hg + 2 Cl +0.26808
[ Hg ( CN ) 4 ] 2− + 2e Hg + 4CN −0.37
[ HgI 4 ] 2− + 2e Hg + 4I −0.04
HgS + 2e Hg + S 2− −0.70
I 2 + 2e 2I +0.5355
In 3+ + 3e In −0.3382
K + + e K −2.931
La 3+ + 3e La −2.52
Li + + e Li −3.04
Lu 3+ + 3e Lu −2.28
Mg 2+ + 2e Mg −2.372
Mn 2+ + 2e Mn −1.185
MnO 2 + 2H 2 O + 2e Mn ( OH ) 2 + 2OH −0.05
MnO 4 + 2H 2 O + 3e MnO 2 + 4OH +0.558
MnO 2 + 4 H + + 2 e Mn 2+ + 2 H 2 O +1.23
MnO 4 + 8 H + + 5 e Mn 2+ + 4 H 2 O +1.507
Na + + e Na −2.71
Nd 3+ + 3e Nd −2.323
Ni 2+ + 2e Ni −0.257
[ Ni ( NH 3 ) 6 ] 2+ + 2e Ni + 6NH 3 −0.49
NiO 2 + 4 H + + 2 e Ni 2+ + 2 H 2 O +1.593
NiO 2 + 2H 2 O + 2e Ni ( OH ) 2 + 2OH +0.49
NiS + 2e Ni + S 2− +0.76
NO 3 + 4 H + + 3 e NO + 2 H 2 O +0.957
NO 3 + 3 H + + 2 e HNO 2 + H 2 O +0.92
NO 3 + H 2 O + 2e NO 2 + 2OH +0.10
Np 3+ + 3e Np −1.856
O 2 + 2H 2 O + 4e 4OH +0.401
O 2 + 2 H + + 2 e H 2 O 2 +0.695
O 2 + 4 H + + 4 e 2 H 2 O +1.229
Pb 2+ + 2e Pb −0.1262
PbO 2 + SO 4 2− + 4 H + + 2 e PbSO 4 + 2 H 2 O +1.69
PbS + 2e Pb + S 2− −0.95
PbSO 4 + 2e Pb + SO 4 2− −0.3505
Pd 2+ + 2e Pd +0.987
[ PdCl 4 ] 2− + 2e Pd + 4Cl +0.591
Pt 2+ + 2e Pt +1.20
[ PtBr 4 ] 2− + 2e Pt + 4Br +0.58
[ PtCl 4 ] 2− + 2e Pt + 4Cl +0.755
[ PtCl 6 ] 2− + 2e [ PtCl 4 ] 2− + 2Cl +0.68
Pu 3 + 3e Pu −2.03
Ra 2+ + 2e Ra −2.92
Rb + + e Rb −2.98
[ RhCl 6 ] 3− + 3e Rh + 6Cl +0.44
S + 2e S 2− −0.47627
S + 2 H + + 2 e H 2 S +0.142
Sc 3+ + 3e Sc −2.09
Se + 2 H + + 2 e H 2 Se −0.399
[ SiF 6 ] 2− + 4e Si + 6F −1.2
SiO 3 2− + 3H 2 O + 4e Si + 6OH −1.697
SiO 2 + 4 H + + 4 e Si + 2 H 2 O −0.86
Sm 3+ + 3e Sm −2.304
Sn 4+ + 2e Sn 2+ +0.151
Sn 2+ + 2e Sn −0.1375
[ SnF 6 ] 2− + 4e Sn + 6F −0.25
SnS + 2e Sn + S 2− −0.94
Sr 2+ + 2e Sr −2.89
TeO 2 + 4 H + + 4 e Te + 2 H 2 O +0.593
Th 4+ + 4e Th −1.90
Ti 2+ + 2e Ti −1.630
U 3+ + 3e U −1.79
V 2+ + 2e V −1.19
Y 3+ + 3e Y −2.37
Zn 2+ + 2e Zn −0.7618
[ Zn ( CN ) 4 ] 2− + 2e Zn + 4CN −1.26
[ Zn ( NH 3 ) 4 ] 2+ + 2e Zn + 4NH 3 −1.04
Zn ( OH ) 2 + 2e Zn + 2OH −1.245
[ Zn ( OH ) 4 ] 2 + 2e Zn + 4OH −1.199
ZnS + 2e Zn + S 2− −1.40
Zr 4 + 4e Zr −1.539

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Source:  OpenStax, Chemistry. OpenStax CNX. May 20, 2015 Download for free at http://legacy.cnx.org/content/col11760/1.9
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